Kinetics Model of the Thermal Oxidation of Indium Powder
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Abstract
The complete oxidation kinetics of indium powder in air has been studied from thermogravimetric studies under isothermal conditions in the range 858-1173 K. The influence of particle size was analyzed in the 25-375 μm range. We succeeded in carrying out the full oxidation of the powders far above the indium-metal melting point (429.75 K) without apparent coalescence of the particles through the presence of a thin In2O3 layer which confines the liquid metal during the oxidation process. The apparent activation energy obtained from the Arrhenius law was 62.2 kJ mol-1.
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Campus Las Lagunillas</s1><s2>23071 Jaén</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Andalousie</region></placeName></affiliation></author><author><name sortKey="Metz, Renaud" uniqKey="Metz R">Renaud Metz</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>Institut Charles Gerhardt Montpellier, UMR 5253 CNRS-UM2-ENSCM-UMI, Universite Montpellier 2, CC 1700, bât.11 - Bureau 319 - 3eme étage. 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The influence of particle size was analyzed in the 25-375 μm range. We succeeded in carrying out the full oxidation of the powders far above the indium-metal melting point (429.75 K) without apparent coalescence of the particles through the presence of a thin In<sub>2</sub>O<sub>3</sub> layer which confines the liquid metal during the oxidation process. The apparent activation energy obtained from the Arrhenius law was 62.2 kJ mol<sup>-1</sup>.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0030-770X</s0></fA01><fA02 i1="01"><s0>OXMEAF</s0></fA02><fA03 i2="1"><s0>Oxid. met.</s0></fA03><fA05><s2>77</s2></fA05><fA06><s2>1-2</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Kinetics Model of the Thermal Oxidation of Indium Powder</s1></fA08><fA11 i1="01" i2="1"><s1>GARCIA MARTIN (Juan F.)</s1></fA11><fA11 i1="02" i2="1"><s1>SANCHEZ (Sebastián)</s1></fA11><fA11 i1="03" i2="1"><s1>METZ (Renaud)</s1></fA11><fA14 i1="01"><s1>Departamento de Ingeniería Química. 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